|Other names||trizinc diphosphide|
|Molar mass||258.1 g/mol|
|Appearance||dark gray crystals|
|Density and phase||4.6 g/cm3, solid|
|Solubility in water||insoluble|
|Except where noted otherwise, data are given for|
materials in their standard state (at 25 °C, 100 kPa)
Infobox disclaimer and references
Metal phosphides have been used as a means of killing rodents. A mixture of food and zinc phosphide is left where the rodents can eat it. The acid in the digestive system of the rodent reacts with the phosphide to generate the toxic phosphine gas. This method of vermin control has possible use in places where rodents immune to many of the common poisons have appeared. Other pesticides similar to zinc phosphide are aluminium phosphide and calcium phosphide.
Zinc phosphide is typically added to rodent baits in amount of around 0.75-2%. The baits have strong, pungent garlic-like odor characteristic for phosphine liberated by hydrolysis. The odor attracts rodents, but has a repulsive effect on other animals; birds, notably wild turkeys, are not sensitive to the smell. The baits have to contain sufficient amount of zinc phosphide in sufficiently attractive food in order to kill rodents in a single serving; a sublethal dose may cause aversion towards zinc-phosphide baits encountered by surviving rodents in the future.
Rodenticide-grade zinc phosphide usually comes as a black powder containing 75% of zinc phosphide and 25% of antimony potassium tartrate, an emetic to cause vomiting if the material is accidentally ingested by humans or domestic animals. Rat, mouse, guinea pig and rabbit do not have the vomiting reflex so can not vomit it.
- Zinc Phosphide Pesticide Information Profile - Extension Toxicology Network
- EPA Proposed Risk Mitigation Decision for Nine Rodenticides
- Zinc phosphide properties and use in Michigan
- MD0173 - Pesticides in the military