|Name, Symbol, Number||radon, Rn, 86|
|Chemical series||noble gases|
|Group, Period, Block||18, 6, p|
|Standard atomic weight||(222) g·mol−1|
|Electron configuration||[Xe] 4f14 5d10 6s2 6p6|
|Electrons per shell||2, 8, 18, 32, 18, 8|
|Density||(0 °C, 101.325 kPa)|
|Melting point||202 K|
(−71.15 °C, −96 °F)
|Boiling point||211.3 K|
(−61.85 °C, −79.1 °F)
|Critical point||377 K, 6.28 MPa|
|Heat of fusion||3.247 kJ·mol−1|
|Heat of vaporization||18.10 kJ·mol−1|
|Heat capacity||(25 °C) 20.786 J·mol−1·K−1|
|Crystal structure||cubic face centered|
|Electronegativity||no data (scale Pauling)|
|Ionization energies||1st: 1037 kJ/mol|
|Atomic radius (calc.)||120 pm|
|Covalent radius||145 pm|
|Thermal conductivity||(300 K) 3.61 m W·m−1·K−1|
|CAS registry number||10043-92-2|
Radon (pronounced /ˈreɪdɒn/) is a chemical element that has the symbol Rn and atomic number 86. Radon is a radioactive noble gas that is formed by the decay of radium. It is one of the heaviest gases and is considered to be a health hazard. The most stable isotope is 222Rn which has a half-life of 3.8 days and is used in radiotherapy. Radon is a significant contaminant that affects indoor air quality worldwide. Radon gas from natural sources can accumulate in buildings and reportedly causes 21,000 lung cancer deaths per year in the United States alone.
Essentially chemically inert but radioactive, radon is the heaviest noble gas and one of the heaviest gases at room temperature. At standard temperature and pressure radon is a colorless gas, but when it is cooled below its freezing point (202 K ; −71 °C ; −96 °F) it has a brilliant phosphorescence which turns yellow as the temperature is lowered, and becomes orange-red at the temperatures air liquefies (below 93 K ; −180 °C).
Natural radon concentrations in Earth's atmosphere are so low that radon-rich water in contact with the atmosphere will continually lose radon by volatilization. Hence, ground water has a higher concentration of 222Rn than surface water, because the radon is continuously produced by radioactive decay of 226Ra present in rocks. Likewise, the saturated zone of a soil frequently has a higher radon content than the unsaturated zone because of diffusional losses to the atmosphere. Radon is a health hazard as exposure can cause lung cancer.
Radon (named after radium) was discovered in 1900 by Friedrich Ernst Dorn, who called it radium emanation. In 1908 William Ramsay and Robert Whytlaw-Gray, named it niton (Latin nitens meaning "shining"; symbol Nt) and isolated it, determined its density, and determined that it was the heaviest known gas. It has been called "radon" since 1923.
The first major studies of the health concern occurred in the context of uranium mining, first in the Joachimsthal region of Bohemia and then in the Southwestern United States during the early Cold War. Because radon is a product of uranium, uranium mines may have high concentrations of radon and its highly radioactive daughter products. Many uranium miners in the Four Corners region contracted lung cancer and other pathologies as a result of high levels of exposure to radon in the mid-1950s. The increased incidence of lung cancer was particularly pronounced among Native American and Mormon miners, because those groups normally have low rates of lung cancer. Safety standards requiring expensive ventilation were not widely implemented or policed during that period.
The danger of radon exposure in dwellings was discovered in 1984 with the case of Stanley Watras, an employee at the Limerick nuclear power plant in Pennsylvania. Watras set off the radiation alarms on his way into work for two weeks straight while authorities searched for the source of the contamination. They were shocked to find that the source was astonishingly high levels of radon, around 100,000 Bq/m³ (2,700 pCi/L), in his house's basement and it was not related to the nuclear plant. The risks associated with living in his house were estimated to be equivalent to smoking 135 packs of cigarettes every day. Following this event, which was highly publicized, national radon safety standards were set, and radon detection and ventilation became a standard homeowner concern.
On average, there is one atom of radon in 1 x 1021 molecules of air. Radon can be found in some spring waters and hot springs. The towns of Boulder, Montana, and Misasa; Bad Kreuznach, Germany, as well as the country of Japan boast radium-rich springs which emit radon.
Radon emanates naturally from the ground all over the world, particularly in regions with soils containing granite or shale. However, not all granitic regions are prone to high emissions of radon. Depending on how houses are built and ventilated, radon may accumulate in basements and dwellings. The highest average radon concentrations in counties in the U.S. are found in Iowa and in the Appalachian Mountain areas in southeastern Pennsylvania.  Some of the highest readings ever have been recorded in the Irish town of Mallow, County Cork prompting local fears regarding lung cancer.
Radon, along with other noble gases krypton and xenon, is also produced during the operation of nuclear power plants. A small fraction of it leaks out of the fuel, through the cladding and into the cooling water, from which it is scavenged. It is then routed to a holding tank where it remains for a large number of half-lives. It is finally purged to the open air through a tall stack which is carefully monitored for radiation level.
The European Union recommends that action should be taken starting from concentrations of 400 Bq/m³ (11 pCi/L) for old houses and 200 Bq/m³ (5 pCi/L) for new ones. After publication of the North American and European Pooling Studies, Health Canada has proposed a new guideline that lowers their action level from 800 to 200 Bq/m³ (22 to 5 pCi/L). The United States Environmental Protection Agency (EPA) strongly recommends action for any house with a concentration higher than 148 Bq/m³ (4 pCi/L), and encourages action starting at 74 Bq/m³ (2 pCi/L). EPA radon risk level tables including comparisons to other risks encountered in life are available in their citizen's guide. Nearly one in 15 homes in the U.S. has a high level of indoor radon according to their statistics. The U.S. Surgeon General and EPA recommend all homes be tested for radon.
Radon emitted from the ground has been shown to accumulate in the air if there is a meteorological inversion and little wind.
In 1971, Apollo 15 passed 110 kilometers above the Aristarchus plateau on the Moon, and detected a significant rise in alpha particles thought to be caused by the decay of radon-222. The Lunar Prospector later confirmed the emissions.
There are twenty known isotopes of radon. The most stable isotope is 222Rn, which is a decay product (daughter product) of 226Ra, has a half-life of 3.823 days and emits alpha particles. 220Rn is a natural decay product of thorium and is called “thoron.” It has a half-life of 55.6 seconds and also emits alpha radiation. 219Rn is derived from actinium, is called “actinon,” is an alpha emitter and has a half-life of 3.96 seconds.
The full decay series of 238U which produces natural radon is as follows (with half-lives):
238U (4.5 x 109 yr), 234Th (24.1 days), 234Pa (1.18 min), 234U (250,000 yr), 230Th (75,000 yr), 226Ra (1,600 yr), 222Rn (3.82 days), 218Po (3.1 min), 214Pb (26.8 min), 214Bi (19.7 min), 214Po (164 µs), 210Pb (22.3 yr), 210Bi (5.01 days), 210Po (138 days), 206Pb (stable).
In the United States and Europe there are a few "radon spas," where people sit for minutes or hours in a high-radon atmosphere in the belief that low doses of radiation will invigorate or energize them. In addition personal testimonies of arthritis relief and other benefits, there is some (very limited) scientific evidence for this belief, known as hormesis. However, the general scientific community finds it unsubstantiated. There is no known biological mechanism by which such an effect could occur. In addition, it conflicts with the internationally recognized standard that there is no safe threshold for radiation exposure and that exposure should be limited to that "as low as reasonably achievable" (ALARA).
Radioactive water baths have been applied since 1906 in Jáchymov, Czech Republic, but even before radon discovery they were used in Bad Gastein, Austria. Hot radium-rich spring releasing radon is also used in traditional Japanese onsen in Misasa, Tottori prefecture. Drinking therapy is applied in Bad Brambach, Germany. Inhalation therapy is carried out in Gasteiner-Heilstollen, Austria, in Kowary, Poland and in Boulder, Montana, United States.
Because of radon's rapid loss to air and comparatively rapid decay, radon is used in hydrologic research that studies the interaction between ground water and streams. Any significant concentration of radon in a stream is a good indicator that there are local inputs of ground water.
Some researchers have looked at elevated soil-gas radon concentrations, or rapid changes in soil or groundwater radon concentrations, as a predictor for earthquakes. Results have been generally unconvincing but may ultimately prove to have some limited use in specific locations.
Radon soil-concentration has been used in an experimental way to map buried close-subsurface geological faults, because concentrations are generally higher over the faults. Similarly it has found some limited use in geothermal prospecting.
Radon emanation from the soil varies with soil type and with surface uranium content, so outdoor radon concentrations can be used to track air masses to a limited degree. This fact has been put to use by some atmospheric scientists.
Radon is a known pollutant emitted from geothermal power stations, though it disperses rapidly, and no radiological hazard has been demonstrated in various investigations. The trend in geothermal plants is to reinject all emissions by pumping deep underground, and this seems likely to ultimately decrease such radon hazards further. Radon is also used in the dating of oil-containing soils because radon has a high affinity of oil-like substances.
Health effects and epidemiology
The general effects of radon to the human body are caused by its radioactivity and consequent risk of radiation-induced cancer. As an inert gas, radon has a low solubility in body fluids which lead to a uniform distribution of the gas throughout the body. Radon gas and its solid decay products are carcinogens. The greatest health risks come from exposure to the inhaled solid radon gas decay products that are produced during the radioactive decay of radon gas. Two of these decay products, polonium-218 and 214, present a significant radiologic hazard. Once the radioactive decay products are inhaled into the lung, they undergo further radioactive decay, releasing small bursts of energy in the form of alpha particles that can either cause DNA breaks or create free radicals.
Based on studies carried out by the National Academy of Sciences in the United States, radon is the second most common cause of lung cancer after cigarette smoking, accounting for 15,000 to 22,000 cancer deaths per year in the U.S. The Surgeon General of the United States has reported that over 20,000 Americans die each year of radon-related lung cancer. The United States Environmental Protection Agency (EPA) recommends homes be fixed if an occupant's long-term exposure will average 4 picocuries per liter (pCi/L) (148 Bq m−3) or higher.
The most elaborate case-control epidemiologic radon study performed by R. William Field and colleagues demonstrated a 50% increased lung cancer risk with prolonged radon exposure at the EPA's action level of 4 pCi/L. Iowa has the highest average radon concentrations in the nation and a very stable population which added to the strength of the study. Pooled epidemiologic radon studies have also shown an increased lung cancer risk from radon below the EPA's action level of 4 pCi/L.
Testing and mitigation
Radon test kits are commercially available. The kit includes a collector that the user hangs in the lowest livable floor of the house for 2 to 7 days. The user then sends the collector to a laboratory for analysis. The National Environmental Health Association provides a list of radon measurement professionals. Long term kits, taking collections for up to one year, are also available. An open land test kit can test radon emissions from the land before construction begins. The EPA and the National Environmental Health Association have identified 15 types of radon testing. A Lucas cell is one type of device.
Radon levels fluctuate naturally. An initial test might not be an accurate assessment of your home's average radon level. Transient weather can affect short term measurements. Therefore, a high result (over 4 pc/l) justifies repeating the test before undertaking more expensive abatement projects. Measurements between 4 and 10 pc/l warrant a long term radon test. Measurements over 10 pc/l warrant only another short term test so that abatement measures are not unduly delayed. Purchasers of real estate are advised to delay or decline a purchase if the seller has not successfully abated radon to 4 pc/l or less.
The National Environmental Health Association administers a voluntary National Radon Proficiency Program for radon professionals consisting of individuals and companies wanting to take training courses and examinations to demonstrate their competency. A list of mitigation service providers is available. Indoor radon can be mitigated by sealing basement foundations, water drainage, or by sub-slab de-pressurization. In severe cases, mitigation can use air pipes and fans to exhaust sub-slab air to the outside. Indoor ventilation systems are more effective, but exterior ventilation can be cost-effective in some cases. Modern construction that conserves energy by making homes air tight exacerbates the risks of radon exposure if radon is present in the home. Older homes with more porous construction are more likely to vent radon naturally. Ventilation systems can be combined with a heat exchanger to recover energy in the process of exchanging air with the outside. Homes built on a crawl space can benefit from a radon collector installed under a radon barrier (a sheet of plastic that covers the crawl space).
- S. Darby, D. Hill, R. Doll (2001). "Radon: A likely carcinogen at all exposures". Annals of Oncology. 12 (10): 27. doi:10.1023/A:1012518223463.
- Radon Occurrence and Health Risk, R. William Field, Department of Occupational and Environmental Health, University of Iowa.
- It's Your Health - Radon, Health Canada
- "Radiation information: radon". United States Environmental Protection Agency. Oct 2006. Retrieved 2007-05-25.
- A Citizen's Guide to Radon: The Guide to Protecting Yourself and Your Family from Radon, United States Environmental Protection Agency.
- Daniel J. Steck, R. William Field, and Charles F. Lynch, "Exposure to Atmospheric Radon", Environmental Health Perspectives, Volume 107, Number 2, February 1999. Online version
- Stein, L. (1970). Science 168: 362.
- Pitzer, K. S. et al. (1975). J. Chem. Soc., Chem. Commun. 1760.
- Lindgren, 1989
- Field, R. William (1999). "Radon Occurrence and Health Risk" (PDF). Retrieved 2007-08-17.
- National Cancer Institute (2004-07-13). "Radon and Cancer: Questions and Answers". Retrieved 2007-08-17.
- "Surgeon General Releases National Health Advisory On Radon". 2005-01-13. Retrieved 2007-08-17.
- EPA (2007-08-08). "United States Environmental Protection Agency: Radon". Retrieved 2007-08-17.
- Field, R. W. (2000). "Residential radon gas exposure and lung cancer: The Iowa radon lung cancer study" (PDF). American Journal of Epidemiology. 151 (11): 1091–1102. PMID 10873134. Unknown parameter
- University of Iowa News Release (2006-05-05). "Journal on Landmark Radon Exposure Studies Co-edited By UI Researcher". Retrieved 2007-08-17.
- Krewski, D. "Residential radon and risk of lung cancer: A combined analysis of 7 North American case-control studies" (PDF). Epidemiology. 16 (2): 137–45. doi:10.1097/01.ede.0000152522.80261.e3. Unknown parameter
- Smith, B. J. (2007). "Iowa radon leukaemia study: a hierarchical population risk model for spatially correlated exposure measured with error". Statistical Medicine. E-published. PMID 17373673. Unknown parameter
- Rericha, V (2007). "Incidence of leukemia, lymphoma, and multiple myeloma in Czech uranium miners: a case-cohort study". Environmental Health Perspectives. 115 (4): A184–5. PMID 16759978. Unknown parameter
|Wikimedia Commons has media related to Radon.|
|40x40px||Look up radon in Wiktionary, the free dictionary.|
- ATSDR - Case Studies in Environmental Medicine: Radon Toxicity U.S. Department of Health and Human Services (public domain)
- Iowa Radon Lung Cancer Study
- Los Alamos National Laboratory - Radon
- USGS Periodic Table - Radon
- EPA Iowa Radon Study
- World Health Organization International Radon Project
- Radon Occurrence and Health Risks
- WebElements.com - Radon
- U.S. Environmental Protection Agency — Indoor Air Radon
- (U.S.) National Safety Council information
- U.K. Health Protection Agency information
- Ask TreeHugger: What Do Radon Tests Mean?
- Radon Removal
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