Magnesite
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| Magnesite | |
|---|---|
| Image:Mineraly.sk - magnezit.jpg |
|
| General | |
| Category | Mineral |
| Chemical formula | magnesium carbonate:MgCO3 |
| Identification | |
| Color | White |
| Crystal habit | usually massive, rarely as rhombohedrons or hexagonal prisms |
| Crystal system | trigonal; bar 3 2/m |
| Cleavage | [1011] Perfect, [1011] Perfect, [1011] Perfect |
| Fracture | Brittle - Conchoidal |
| Mohs Scale hardness | 3.5 - 5 |
| Luster | Vitreous |
| Refractive index | Uniaxial (-) nω=1.508 - 1.510 nε=1.700 |
| Streak | white |
| Specific gravity | 3.0 - 3.2 |
| Fusibility | infusible |
| Solubility | Effervesces in hot HCl |
Magnesite is magnesium carbonate, MgCO3. Iron (as Fe2+) substitutes for magnesium (Mg) with a complete solution series with siderite, FeCO3. Calcium, manganese, cobalt, and nickel may also occur in small amounts. Dolomite, (Mg,Ca)CO3, is almost indistinguishable from magnesite.
Contents |
Occurrence
Magnesite occurs as veins in and an alteration product of ultramafic rocks, serpentinite and other magnesium rich rock types in both contact and regional metamorphic terranes. These magnesites often are cryptocrystalline and contain silica as opal or chert.
Magnesite is also present within the regolith above ultramafic rocks as a secondary carbonate within soil and subsoil, where it is deposited as a consequence of dissolution of magnesium-bearing minerals by carbon dioxide within groundwaters.
Formation
Magnesite can be formed via talc carbonate metasomatism of peridotite and other ultrabasic rocks. Magnesite is formed via carbonation of olivine in the presence of water and carbon dioxide, and is favored at moderate temperatures and pressures typical of greenschist facies;
Magnesite can also be formed via the carbonation of magnesian serpentine (lizardite) via the following reaction:
Serpentine + carbon dioxide → Talc + magnesite + Water
Forsterite magnesia-rich olivine compositions favor production of magnesite from peridotite. Fayalitic (iron-rich) olivine favors production of magnetite-magnesite-silica compositions.
Magnesite can also be formed from metasomatism in skarn deposits, in dolomitic limestones, associated with wollastonite, periclase, and talc.
Uses
Magnesite can be used as a slag former in steelmaking furnaces, in conjunction with lime, in order to protect the magnesium oxide lining. It can also be used as a catalyst and filler in the production of synthetic rubber and in the preparation of magnesium chemicals and fertilizers.
Similar to the production of lime, magnesite can be burned in the presence of charcoal to produce MgO, otherwise known as periclase. Such periclase is an important product in refractory materials.
References and external links
- Dana's Manual of Mineralogy ISBN 0-471-03288-3
- Smithsonian Rock and Gem ISBN 0-7566-0962-3
- Mineral Galleries
- Webmineral.com
- Mindat.org
- Minerals.netda:Magnesiumcarbonat
de:Magnesiumcarbonat fi:Magnesiitti fr:Magnésite it:Magnesite (minerale) hu:Magnezit he:מגנזיט ja:菱苦土鉱 nl:Magnesietsk:magnezitsr:Магнезијум карбонат
Acknowledgement and Attribution Regarding Sources of Content
Some of the initial content on this page may be incorporated in part from copyleft sources in the public domain including wikis such as Wikipedia and AskDrWiki. Drug information for patients came from the The National Library of Medicine. Infectious disease information may have come from the Centers for Disease Control (CDC). Differential Diagnoses are drawn from clinicians as well as an amalgamation of 3 sources: 1.The Disease Database; 2. Kahan, Scott, Smith, Ellen G. In A Page: Signs and Symptoms. Malden, Massachusetts: Blackwell Publishing, 2004:3; 3. Sailer, Christian, Wasner, Susanne. Differential Diagnosis Pocket. Hermosa Beach, CA: Borm Bruckmeir Publishing LLC, 2002:7 .
