Tungsten carbide

Monotungsten carbide, WC, or Ditungsten Carbide, W₂C, is a chemical compound containing tungsten and carbon, similar to titanium carbide.

Chemical and physical properties

Tungsten is a very hard and dense metal, mined from Wolframite ore and symbolized by a (W) on the periodic table of elements. It melts at an extraordinary 6,192 °F (3422 °C) – the highest melting point of all metals. On its own, tungsten is vulnerable to scratches and damage just like any other metal, such as titanium and steel. Tungsten does not gain its extreme hardness until it is combined with a carbon alloy, transforming it into tungsten carbide (WC) with a hardness between 8.5 and 9.5 on the Mohs hardness scale. Tungsten carbide is four times harder than titanium, twice as hard as steel, is virtually unscratchable, and has been widely used for decades in industrial applications such as cutting tools, mining machinery, and rocket engine nozzles. Its extreme hardness makes it useful in the manufacture of cutting tools, abrasives and bearings, as a cheaper and more heat-resistant alternative to diamond. Tungsten carbide is also used as a scratch-resistant material for jewelry including watch bands and wedding rings.

Applications

Machine tools

Carbide cutting surfaces are often useful when machining through materials such as carbon steel or stainless steel, as well as in situations where other tools would wear away, such as high-quantity production runs. Sometimes, carbide will leave a better finish on the part, and allow faster machining. Carbide tools can also withstand higher temperatures than standard high speed steel tools. The material is usually tungsten-carbide cobalt, also called "cemented carbide", a metal matrix composite where tungsten carbide particles are the aggregate and metallic cobalt serves as the matrix. The process of combining tungsten carbide with cobalt is referred to as sintering or Hot Isostatic Pressing (HIP). During this process cobalt eventually will be entering the liquid stage and WC grains (>> higher melting point) remain in the solid stage. As a result of this process cobalt is embedding/cementing the WC grains and thereby creates the metal matrix composite with its distinct material properties. The naturally ductile cobalt metal serves to offset the characteristic brittle behavior of the tungsten carbide ceramic, thus raising its toughness and durability. Such parameters of tungsten carbide can be changed significantly within the carbide manufacturers sphere of influence, primarily determined by grain size, cobalt content, dotation (e.g. alloy carbides) and carbon content.

Machining with carbide can be difficult, as carbide is more brittle than other tool materials, making it susceptible to chipping and breaking. To offset this, many manufacturers sell carbide inserts and matching insert holders. With this setup, the small carbide insert is held in place by a larger tool made of a less brittle material (usually steel). This gives the benefit of using carbide without the high cost of making the entire tool out of carbide. Most modern face mills use carbide inserts, as well as some lathe tools and endmills.

To increase the life of carbide tools, they are sometimes coated. Four such coatings are TiN (titanium nitride), TiC (titanium carbide), Ti(C)N (titanium carbide-nitride), and TiAlN (Titanium Aluminum Nitride). (Newer coatings, known as DLC (Diamond Like Coating) are beginning to surface, enabling the cutting power of diamond without the unwanted chemical reaction between real diamond and iron.) Most coatings generally increase a tool's hardness and/or lubricity. A coating allows the cutting edge of a tool to cleanly pass through the material without having the material gall (stick) to it. The coating also helps to decrease the temperature associated with the cutting process and increase the life of the tool. The coating is usually deposited via thermal CVD and, for certain applications, with the mechanical PVD method. However if the deposition is performed at too high temperature, an eta phase of a Co₆W₆C tertiary carbide forms at the interface between the carbide and the cobalt phase, facilitating adhesion failure of the coating.

Military

Tungsten carbide is often used in armor-piercing ammunition, especially where depleted uranium is not available or not politically acceptable. The first use of W₂C projectiles occurred in Luftwaffe tank-hunter squadrons, which used 37 mm autocannon equipped Ju-87G Stuka attack planes to destroy Soviet T-34 tanks in WWII. Owing to the limited German reserves of tungsten, W₂C material was reserved for making machine tools and small numbers of projectiles for the most elite combat pilots, like Hans Rudel. It is an effective penetrator due to its high hardness value combined with a very high density.

Tungsten carbide ammunition can be of the sabot type (a large arrow surrounded by a discarding push cylinder) or a subcaliber ammunition, where copper or other relatively soft material is used to encase the hard penetrating core, the two parts being separated only on impact. The latter is more common in small-caliber arms, while sabots are usually reserved for artillery use.

Tungsten carbide is also an effective neutron reflector and as such was used during early investigations into nuclear chain reactions, particularly for weapons. A criticality accident occurred at Los Alamos National Laboratory on 21 August 1945 when Harry K. Daghlian, Jr. accidentally dropped a tungsten carbide brick onto a plutonium sphere causing the sub-critical mass to go critical with the reflected neutrons.

Sports

Hard carbides, especially tungsten carbide, are used by athletes, generally on poles which impact hard surfaces. Trekking poles, used by many hikers for balance and to reduce pressure on leg joints, generally use carbide tips in order to gain traction when placed on hard surfaces (like rock); such carbide tips last much longer than other types of tips. Rocks along many popular hiking trails, such as the Appalachian Trail and Pacific Crest Trail, are scratched and pockmarked from hundreds or thousands of impacts from pole tips.

While ski pole tips are generally not made of carbide, since they do not need to be especially hard even to break through layers of ice, rollerski tips usually are. Roller skiing emulates cross country skiing and is used by many skiers to train during warm weather months. Because skiers require traction on bitumen (asphalt) carbide tips are used in the sport.

Some tire manufacturers, such as Nokian and Schwalbe, offer bicycle tires with tungsten carbide studs for better traction on ice. These are generally preferred over steel studs because of their wear resistance.

Domestic

Tungsten carbide is used as the rotating ball in the tips of ballpoint pens to disperse ink during writing.

Tungsten carbide can now be found in the inventory of some jewelers, most notably as the primary material in men's wedding bands. When used in this application the bands appear with a lustrous dark hue often buffed to a mirror finish. The finish is highly resistant to scratches and scuffs, holding its mirror-like shine for years. A danger associated with this use is the occasional need to remove rings in the course of emergency medical treatment. Emergency rooms are usually equipped with jewelers' saws that can easily cut through gold and silver rings without injuring the patient when the ring cannot be slipped off easily. However, these saws are incapable of cutting through tungsten carbide.

Tungsten carbide rings can actually be removed in an emergency situation by cracking them into pieces with standard vice grip–style locking pliers. Although standard ring cutting tools cannot be used due to the hardness of this material, there are specialty cutters available that are just as effective on tungsten carbide as they are on gold and platinum.

Many manufacturers of this emerging jewelry state that the use of a cobalt binder may cause unwanted reactions between the cobalt and the natural oils on human skin. Skin oils cause the cobalt to leach from the material. This is said to cause possible irritation of the skin and permanent staining of the jewelry itself. Many manufacturers now advertise that their jewelry is "cobalt free". This is obtained by substituting the cobalt with nickel as a binder.

External links

• International Chemical Safety Card 1320
• NIOSH Pocket Guide to Chemical Hazards
• Memsnet: Properties of tungsten carbide
• Tungsten Carbide Products
• Tungsten Carbide Powder