Silver(I) iodide
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| Thermochemistry | |
|---|---|
| Image:Silver-iodide-3D-balls.png | |
| Other names | Silver(I) iodide |
| Identifiers | |
| CAS number | |
| Properties | |
| Molecular formula | AgI |
| Molar mass | 234.773 g/mol |
| Appearance | yellow, crystalline solid |
| Density | 5.675 g/cm3, solid |
| Melting point |
552°C |
| Boiling point |
1506°C |
| Solubility in water | 3x10-7g/100mL (20 °C) |
| Thermochemistry | |
| Std enthalpy of formation ΔfH | -62.4 kJ/mol at 1 atm |
| Hazards | |
| EU classification | not listed |
| NFPA 704 |
|
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references | |
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Silver iodide (AgI) is a chemical compound used in photography and as an antiseptic in medicine. Silver iodide is highly insoluble in water and has a crystalline structure similar to that of ice, allowing it to induce freezing (heterogeneous nucleation) in cloud seeding for the purpose of rainmaking.
The crystalline structure adopted by silver iodide changes with temperature. The following phases are known:[1]
- Up to 420K (147 °C), AgI exists in the β-phase, which has a wurtzite structure.
- Above 420K (147 °C), AgI undergoes a transition to the α-phase, which has a body-centered cubic structure and has the silver ions distributed randomly between 2-, 3-, and 4-coordinate sites.
- A metastable γ-phase also exists below 420K, which has a zinc blende structure.
Silver iodide as a fast ion conductor
The transition between the β and α forms represents the melting of the silver (cation) sublattice. The entropy of fusion (melting) for α-AgI is approximately half that for sodium chloride (a typical ionic solid). This can be rationalised by noting that the AgI crystalline lattice has essentially already partly melted in the transition between α and β forms. Adding the entropy of transition from α-AgI to β-AgI to the entropy of fusion gives a value that is much closer to the entropy of fusion for sodium chloride.
References
In Media
In the television series The Batman, Poison Ivy used Silver Iodide to create rain, so that she could populate Gotham City with her new breed of plants, that assisted her in taking over the city.
External links
ar:يوديد فضة de:Silberiodideo:Arĝenta jodido nl:Zilverjodide ja:ヨウ化銀
Acknowledgement and Attribution Regarding Sources of Content
Some of the initial content on this page may be incorporated in part from copyleft sources in the public domain including wikis such as Wikipedia and AskDrWiki. Drug information for patients came from the The National Library of Medicine. Infectious disease information may have come from the Centers for Disease Control (CDC). Differential Diagnoses are drawn from clinicians as well as an amalgamation of 3 sources: 1.The Disease Database; 2. Kahan, Scott, Smith, Ellen G. In A Page: Signs and Symptoms. Malden, Massachusetts: Blackwell Publishing, 2004:3; 3. Sailer, Christian, Wasner, Susanne. Differential Diagnosis Pocket. Hermosa Beach, CA: Borm Bruckmeir Publishing LLC, 2002:7 .
